|I||Basic Concepts of Chemistry||11|
|II||Structure of Atom|
|III||Classification of Elements & Periodicity in Properties||4|
|IV||Chemical Bonding and Molecular Structure||21|
|V||States of Matter: Gases and Liquids|
|XI||Some p-Block Elements|
|XII||Organic Chemistry: Basic Principles & Techniques||18|
General Introduction: Importance and scope of chemistry.Nature of matter, laws of chemical combination, Dalton’s atomic theory: concept of elements, atoms and molecules.
Atomic and molecular masses, mole concept and molar mass, percentage composition, empirical and molecular formula, chemical reactions, stoichiometry and calculations based on stoichiometry.
Concepts of System and types of systems, surroundings, work, heat, energy, extensive and intensive properties, state functions.First law of thermodynamics -internal energy and enthalpy, heat capacity and specific heat, measurement of ΔU and ΔH, Hess’s law of constant heat summation, enthalpy of bond dissociation, combustion, formation, atomization, sublimation, phase transition, ionization, solution and dilution. Second law of Thermodynamics (brief introduction)
Introduction of entropy as a state function, Gibb’s energy change for spontaneous and non-spontaneous processes, criteria for equilibrium.
Third law of thermodynamics (brief introduction).
General Introduction to p – Block Elements
Alkanes – Nomenclature, isomerism, conformation (ethane only), physical properties, chemical reactions including free radical mechanism of halogenation, combustion and pyrolysis.
Alkenes – Nomenclature, structure of double bond (ethene), geometrical isomerism, physical properties, methods of preparation, chemical reactions: addition of hydrogen, halogen, water, hydrogen halides (Markownikov’s addition and peroxide effect), ozonolysis, oxidation, mechanism of electrophilic addition.
Alkynes – Nomenclature, structure of triple bond (ethyne), physical properties, methods of preparation, chemical reactions: acidic character of alkynes, addition reaction of – hydrogen, halogens, hydrogen halides and water.
Aromatic Hydrocarbons: Introduction, IUPAC nomenclature, benzene: resonance, aromaticity, chemical properties: mechanism of electrophilic substitution. nitration, sulphonation, halogenation, Friedel Craft’s alkylation and acylation, directive influence of functional group in monosubstituted benzene. Carcinogenicity and toxicity.