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Question

Arrange Mg, Al, Si, P and S in the correct order of their ionisation potentials.

A
P < S < Si < Mg < Al
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B
P > S > Si > Mg > Al
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C
P > S > Al > Mg > Si
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D
S > P > Al > Mg > Si
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Solution

The correct option is B P > S > Si > Mg > Al
Answer: P > S > Si > Mg > Al

In the third period of the periodic table,

Element

Valence Shell Configuration

Na

3s1

Mg

3s2

Al

3s23p1

Si

3s23p2

P

3s23p3

S

3s23p4


Ideally, from left to right, ionization enthalpy increases. But we see exceptions in (Mg, Al) & (P, S) where the element to the left, Mg and P, have higher ionization enthalpies compared to their respective immediate neighbors due to stable electronic configuration.

So, the order will be: P > S > Si > Mg > Al

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