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Question

How do you solve enthalpy problems?


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Solution

Normally, we calculate the enthalpy change that occurs during a chemical reaction. An enthalpy change is the amount of heat absorbed or released as a chemical reaction takes place. Based on the information available to you, you carry out the calculation differently. Here, let us discuss the different ways we use to calculate the enthalpy change in a reaction:

Simple Method

When we know the enthalpy of the products and reactants, we can use the following formula to calculate the overall enthalpy change:

H=Hproducts-Hreactant

Let us consider an example of sodium chloride(NaCl) which is formed by the addition of sodium ion and chloride ion.

Ionic sodium has an enthalpy of -239.7kJ/mol, chloride ion has enthalpy -167.4kJ/moll and Sodium chloride (table salt) has an enthalpy of -411kJ/mol

Now inserting these values in the above formula, we get

-411kJ/mol-(-239.7kJ/mol-167.4kJ/mol)-411kJ/mol-(-407.1kJ/mol)-411kJ/mol+407.1kJ/mol=-3.9kJ/mol

We understand that the formation of salt releases almost 4kJ of energy per mole from the calculation.

Calculating Enthalpy Change during Phase Transition

When substances change from one state to another, there are specific enthalpies involved in these changes. For water, the enthalpy of melting is. Suppose you heat the ice from 250K until it melts, and then heat the water to 300K. The enthalpy change for the heating parts is just the heat required, so you can find it using:

H=nCT

Where (n) is the number of molecules, (T) is the change in temperature and (C) is the specific heat.


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