Zener breakdown occurs in a p-n junction having p and n both
heavily doped and have a narrow depletion layer
Explanations for correct option b:
ZENER DIODE BREAKDOWN
DOPING OF DIODE
DEPLETION LAYER
Therefore, in a P-N junction, while the Zener diode breaks down, p and n are highly doped with a narrow depletion layer.
Hence, the correct option is (C).