JEE Main 2021 March 16 Shift 1 Chemistry Question Paper with Solutions

JEE Main 2021 March 16th shift 1 Chemistry question paper with solutions are available here. Students can view the questions and also check the correct answers to each of them. The question paper given here will further help students to get familiar with the JEE Main 2021 exam pattern and they will also get to know the marking scheme and the type of questions asked in the entrance exam.

JEE Main 2021 March 16 – Shift 1 Chemistry Question Paper with Solutions

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JEE Main 2021 March 16th Shift 1 Chemistry Question Paper

SECTION-A

Question 1. Among the following, the aromatic compounds are:

JEE Main 2021 March 16th Shift-1 Chemistry Paper Question 1

Choose the correct answer from the following options:

a. (A) and (B) only
b. (A), (B) and (C) only
c. (B), (C) and (D) only
d. (B) and (C) only

Answer: (d)

JEE Main 2021 March 16th Shift-1 Chemistry Paper Question 1 solution

Question 2. Given below are two statements:

Statement I: H₂O₂ can act as both oxidizing and reducing agent in the basic medium.

Statement II: In the hydrogen economy, energy is transmitted in the form of dihydrogen.

In the light of the above statements, choose the correct Ans: from the options given below:

a. Statement I is false but statement II is true
b. Both Statement I and Statement II are true
c. Statement I is true but statement II is false
d. Both Statement I and Statement II are false

Answer: (b)

H₂O₂ can act as an oxidizing and reducing agent in both acidic and basic mediums.

Question 3. Which of the following is Lindlar catalyst?

a. Zinc chloride and HCl
b. Partially deactivated palladised charcoal
c. Sodium and Liquid NH₃
d. Cold dilute solution of KMnO₄

Answer: (b

Lindlar’s catalyst ⇒ Pd/CaCo₃ + (CH₃COO)₂ Pb + quinoline

Question 4. In chromatography technique, the purification of a compound is independent of:

a. Length of the column or TLC plate
b. Mobility or flow of solvent system
c. Physical state of the pure compound
d. Solubility of the compound

Answer: (c)

Based on NCERT

Question 5. Which among the following pairs of Vitamins is stored in our body relatively for longer duration?

a. Ascorbic acid and Vitamin D
b. Thiamine and Ascorbic acid
c. Vitamin A and Vitamin D
d. Thiamine and Vitamin A

Answer: (c)

Based on NCERT

Question 6. In the below chemical reaction, intermediate “X” and reagent/condition “A” are:

JEE Main 2021 March 16th Shift-1 Chemistry Paper Question 6

Answer: (c)

Question 7. Which of the following reaction/reactions DOES NOT involve Hoffmann bromamide degradation?

JEE Main 2021 March 16th Shift-1 Chemistry Paper Question 7

Answer: (d)

JEE Main 2021 March 16th Shift-1 Chemistry Paper Question 7 solution

Question 8. A group 15 element, which is a metal and forms a hydride with strongest reducing power among group 15 hydrides. The element is:

a. Bi
b. As
c. P
d. S

Answer: (a)

BiH₃ is the strongest reducing agent among the hydrides of 15 group elements as Bi – H bond dissociation energy is very less.

Question 9. Given below are two statements: One is labelled as Assertion A and the other is labelled as Reason R:

Assertion A: The size of the Bk³⁺ ion is less than the Np³⁺ ion.

Reason R: The above is a consequence of the lanthanoid contraction.

In the light of the above statements, choose the correct Ans: from the options given below:

a. A is false but R is true
b. Both A and R are true but R is not the correct explanation of A
c. A is true but R is false
d. Both A and R are true and R is the correct explanation of A

Answer: (c)

₉₃Np³⁺₉₇Bk³⁺ as atomic no. increase ionic size decreases. It is due to actinoid contraction.

Question 10. The products “A” and “B” formed in the below reactions are:

JEE Main 2021 March 16th Shift-1 Chemistry Paper Question 10

Answer: (a)

Question 11. The type of pollution that gets increased during the day time and in the presence of O₃ is:

a. Global warming
b. Reducing smog
c. Acid rain
d. Oxidizing smog

Answer: (d)

NO + O₂ → NO₂

NO + O₃ → NO₂ + O₂

\(\begin{array}{l}NO_{2}\overset{hv}{\rightarrow}NO + [O]\end{array} \)

O + O₂ → O₃

This O₃ is called bad ozone.

CH₄ + O₂ → CH₂ = O + H₂O

(Vehicle Exhaust)

Question 12. The product “P” in the below reaction is:

JEE Main 2021 March 16th Shift-1 Chemistry Paper Question 12

Answer: (d)

JEE Main 2021 March 16th Shift-1 Chemistry Paper Question 12 solution

Question 13. Match List – I with List – II:

	List-I Industrial process	List-II Application
(a)	Haber’s process	(i)	HNO₃ synthesis
(b)	Ostwald’s process	(ii)	Aluminium extraction
(c)	Contact process	(iii)	NH₃ synthesis
(d)	Hall-Heroult process	(iv)	H₂SO₄synthesis

Choose the correct Ans: from the options given below:

a. (a)-(iv), (b)-(i), (c)-(ii), (d)-(iii)
b. (a)-(ii), (b)-(iii), (c)-(iv), (d)-(i)
c. (a)-(iii), (b)-(iv), (c)-(i), (d)-(ii)
d. (a)-(iii), (b)-(i), (c)-(iv), (d)-(ii)

Answer: (d)

Haber’s process is used for NH₃ manufacture.

N₂ + 3H₂ ⇌ 2NH₃

Ostwald’s process is used for the preparation of HNO₃ by catalytic oxidation of NH₃

The contact process is used for the preparation of H₂SO₄ using V₂O₅ catalyst

Hall Heroult process is used for Al extraction.

Question 14. Given below are two statements:

Statement I: The E^o value for Ce⁴⁺/Ce³⁺ is +1.74 V.

Statement II: Ce is more stable in Ce⁴⁺ state than Ce³⁺ state.

In the light of the above statements, choose the correct Ans: from the options given below:

a. Both Statement I and Statement II are correct
b. Statement I is incorrect but statement II is correct
c. Both Statement I and Statement II are incorrect
d. Statement I is correct but statement II is incorrect

Answer: (d)

Ce⁴⁺ is a good oxidising agent as Ce³⁺ is more stable

Ce^4- + e^– → Ce³⁺

E^o= 1.74 volt

Question 15. Given below are two statements:

Statement I: Both CaCl₂.6H₂O and MgCl₂.8H₂O undergo dehydration on heating.

Statement II: BeO is amphoteric whereas the oxides of other elements in the same group are acidic.

In the light of the above statements, choose the correct Ans: from the options given below:

a. Statement I is true but statement II is false
b. Both Statement I and Statement II are false
c. Statement I is false but statement II is true
d. Both Statement I and Statement II are true

Answer: (b)

\(\begin{array}{l}CaCl_{2}.6H_{2}O\overset{\Delta }{\rightarrow}CaCl_{2} + 6H_{2}O\end{array} \)

MgCl₂.6H₂O → MgCl(OH) + HCl + 5H₂O

Among alkaline earth metal, BeO is amphoteric and the rest are basic oxides.

Question 16. Given below are two statements: One is labelled as Assertion A and the other is labelled as Reason R.

Assertion A: Enol form acetone [CH₃COCH₃] exists in <0.1% quantity. However, the enol forms acetylacetone [CH₃COCH₂OCCH₃] that exists in approximately 15% quantity.

Reason R: Enol form of acetylacetone is stabilized by intramolecular hydrogen bonding, which is not possible in enol form of acetone.

In the light of the above statements, choose the correct statement:

a. A is true but R is false
b. Both A and R are true but R is the correct explanation of A
c. A is false but R is true
d. Both A and R are true but R is not the correct explanation of A

Answer: (b)

JEE Main 2021 March 16th Shift-1 Chemistry Paper Question 16 solution

Question 17. Given below are two statements: One is labelled as Assertion A and the other is labelled as Reason R

Assertion A: The H–O–H bond angle in a water molecule is 104.5^o

Reason R: The lone pair – lone pair repulsion of electrons is higher than the bond pair-bond pair repulsion.

In the light of the above statements, choose the correct Ans: from the options given below:

a. A is false but R is true
b. A is true but R is false
c. Both A and R are true, and R is the correct explanation of A
d. Both A and R are true, but R is not the correct explanation of A

Answer: (c)

JEE Main 2021 March 16th Shift-1 Chemistry Paper Question 17 solution

In water O atom is sp³ hybridized with 2 B.P & 2 L.P

Question 18. Match List – I with List – II:

	List-I Name of oxo acid	List-II Oxidation state of ‘P’
(a)	Hypophosphorous acid	(i)	+5
(b)	Orthophosphoric acid	(ii)	+4
(c)	Hypophosphoric acid	(iii)	+3
(d)	Orthophosphorous acid	(iv)	+2
–	–	(v)	+1

Choose the correct answer from the options given below:

a. (a)-(iv), (b)-(v), (c)-(ii), (d)-(iii)
b. (a)-(v), (b)-(iv), (c)-(ii), (d)-(iii)
c. (a)-(v), (b)-(i), (c)-(ii), (d)-(iii)
d. (a)-(iv), (b)-(i), (c)-(ii), (d)-(iii)

Answer: (c)

Hypophosphorous acidH₃PO₂ +1

Orthophosphoric acid H₃PO₄ +5

Hypophosphoric acid H₄P₂O₆ +4

Orthophosphoric acid H₃PO₃ +3

Question 19. The process that involves the removal of sulphur from the ores is:

a. Refining
b. Roasting
c. Smelting
d. Leaching

Answer: (b)

Roasting removes S as SO₂

S + O₂ → SO₂

Question 20. The functions of antihistamine are:

a. Antiallergic and Analgesic
b. Antacid and antiallergic
c. Antiallergic and antidepressant
d. Analgesic and antacid

Answer: (b)

Based on NCERT

SECTION-B

Question 21. If the equation below is balanced with integer coefficients, the value of c is__________. (Round off to the nearest integer)

2MnO^–₄ + bC₂O^2-₄ + cH⁺ → xMn²⁺ + yCO₂ + zH₂O_.

Answer: 16

16H⁺ + 2MnO₄^–+ 5C₂O₄^2– ⎯→ 2Mn²⁺ + 10CO₂ + 8H₂O

Question 22. Complete combustion of 750 g of an organic compound provides 420 g of CO₂ and 210 g of H₂O. The percentage composition of carbon and hydrogen in organic compounds is 15.3 and _______ respectively. (Round off to the Nearest Integer).

Answer: 3

Liebig method:

% of H-element =
\(\begin{array}{l}\frac{2}{18}\times \frac{Mass\: of\: H_{2}O}{Mass\: of\: compound} \times 100\end{array} \)

=
\(\begin{array}{l}\frac{2}{18}\times \frac{210}{750} \times 100 = 3.11\simeq 3\end{array} \)

Question 23. AB₂ is 10% dissociated in water to A²⁺ and B^–. The boiling point of a 10.0 molal aqueous solution of AB₂ is ____________ ^oC. (Round off to the Nearest Integer).

[Given: Molal elevation constant of water K_b = 0.5 K kg mol^–1 boiling point of pure water = 100^oC]

Answer: 106

ΔT_b= iK_bm

α = i-1 / n-1

0.1 = i-1 / 3-1 {AB₂ ⇌ A²⁺ + 2B^–}

i = 1.2

ΔT_b = 1.2 × 0.5 × 10 = 6

(T_b)_solution = 106°C

Question 24. A certain element crystallizes in a bcc lattice of unit cell edge length 27Å. If the same element under the same conditions crystallises in the fcc lattice, the edge length of the unit cell in Å will be _________. (Round off to the Nearest Integer).

[Assume each lattice point has a single atom]

[Assume √3 = 1.73, √2 = 1.41]

Answer: 33

For BCC unit cell, √3a = 4R

a = 4R/√3 = 27

R = 27√3 / 4

For fcc unit cell

√2a = 4R

a = 4/√2 (27√3 / 4)

a = 27 √3 / √2

a = 33.12 ≈ 33

Question 25. The equivalents of ethylene diamine required to replace the neutral ligands from the coordination sphere of the trans-complex of CoCl₃.4NH₃ is __________. (Round off to the nearest Integer).

Answer: 2

COCl₃.4NH₃ or [CO(NH₃)₄Cl₂]Cl

Question 26. For the reaction A(g) ⇌ B(g) at 495 K, Δ_rG^o = –9.478 kJ mol^–(1)

If we start the reaction in a closed container at 495 K with 22 millimoles of A, the amount of B in the equilibrium mixture is ________millimoles. (Round off to the nearest Integer).

[R = 8.314] mol^–1 K^–1; ln 10 = 2.303]

Answer: 20

ΔG° = –RT ln Keq

–9.478 × 10³ = –495 × 8.314 ln Keq

ln Keq = 2.303 = ln10

So, Keq = 10

Now,

A(g) B(g)

t = 0 22 0

t = t 22–x x

Keq = [B] / [A] = X / (22-X) = 10

x = 20

So, millimoles of B = 20

Question 27. When light of wavelength 248 nm falls on a metal of threshold energy 3.0 eV, the de-Broglie wavelength of emitted electrons is ____________Å. (Round off to the Nearest Integer).

[Use : √3 = 1.73, h = 6.63×10^–34Js

m_e = 9.1×10^-31 kg; c = 3.0×10⁸ms^–1; 1eV = 1.6×10^–19J]

Answer: 9

λ = 248 × 10^–9m

w₀ = 3 × 1.6 × 10^–19J

E = w₀ + K.E.

hc / λ = W₀ + K.E.

K.E =
\(\begin{array}{l}K.E = \frac{6.626\times 10\frac{-34}\times 3\times 10^{8}}{248} – 3\times 1.6\times 10^{-19}\end{array} \)

= 3.2 × 10^–19J

P = √2mK.E.

P =
\(\begin{array}{l}\sqrt{2\times9.1\times10^{-31}\times3.2\times10^{-19}}\end{array} \)

P = 7.63 × 10^–25

∴
\(\begin{array}{l}\lambda = \frac{h}{p}=\frac{6.626\times 10^{-34}}{7.63\times 10^{-25}}\end{array} \)

λ = 8.7 × 10^–10 = 8.7Å 9

Question 28. A 6.50 molal solution of KOH (aq.) has a density of 1.89 g cm^–3The molarity of the solution is __________ moldm^–3 (Round off to the Nearest Integer).

[Atomic masses : K : 39.0 u; O: 16.0 u; H: 1.0 u]

Answer: 9

\(\begin{array}{l}m = \frac{1000\times M}{1000\times d-M\times M_{solute}}\end{array} \)

\(\begin{array}{l}6.5 = \frac{1000\times M}{1890\times M\times 56}\end{array} \)

12285 – 364M = 1000M

1364 M = 12285

M = 9

Question 29. Two salts A₂X and MX have the same value of solubility product of 4.0×10^–12. The ratio of their molar solubilities i.e.
\(\begin{array}{l}\frac{S(A_{2}X)}{S(MX)}\end{array} \)
= _____________. (Round off to the Nearest Integer).

Answer: 50

A₂X(s) ⇌ 2A⁺(aq) + X^2–(aq)

Solubility: (x) mole / L (2x) (x)

⇒ K_sp = 4 × 10^–12 = [A⁺]² [X^–] = 4x³

⇒ x = 10^–4 =
\(\begin{array}{l}S_{A_{2}X}\end{array} \)

MX(s) ⇌ M⁺(aq) + X^–(aq)

Solubility: (y) mole / L (y) (y)

⇒ K_sp =× 4 10^–12 = [M⁺][X^–] = y²

⇒ y = 2 × 10^–6 = S_MX

⇒
\(\begin{array}{l}\frac{S(A_{2}X)}{S(MX)} = \frac{10^{-4}}{2\times 10^{-6}} = 50\end{array} \)

Question 30: The decomposition of formic acid on gold surface follows first order kinetics. If the rate constant at 300 K is 1.0×10^–3 s^–1and the activation energy E_a = 11.488 kJ mol^–1, the rate constant at 200 K is __________×10^–5s^–1.(Round off to the Nearest Integer).

Answer: 10

\(\begin{array}{l}log\frac{K_{2}}{K_{1}}= \frac{E_{a}}{2.303R}\left [ \frac{1}{T_{1}} = \frac{1}{T_{2}}\right]\end{array} \)

\(\begin{array}{l}log\frac{1.0\times 10^{-3}s^{-1}}{K_{1}}=\frac{11.488\times 1000}{2.303\times 8.314}\left [\frac{1}{200}- \frac{1}{300}\right ]\end{array} \)

\(\begin{array}{l}log\frac{10^{-3}}{K_{1}}=600\times \frac{3-2}{600}\end{array} \)

\(\begin{array}{l}log\frac{10^{-3}}{K_{1}}=1\end{array} \)

⇒
\(\begin{array}{l}10 = \frac{10^{-3}}{K_{1}}\end{array} \)

⇒ K₁ = 10^–4

So, x × 10^–5 = 10^–4⇒ x = 10

(Given: R = 8.314 J Mol^–1 K^–1)

JEE Main 2021 March 16 – Shift 1 Chemistry Question Paper with Solutions

JEE Main 2021 March 16 – Shift 1 Chemistry Question Paper with Solutions

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