Formula of Molar Concentration
The molar concentration formula is given by,
Molar Concentration = Amount in Moles / Volume of Solution
Solved Examples
Example 1
Determine the molar concentration of NaOH for the reaction between HCl and NaOH.
Solution:
The balanced chemical equation can be framed as,
HCl + NaOH → NaCl + H2O
For an acid
n(HCl) = (35.0 / 1000 dm3) × 0.250 mol dm-3
          = 8.75 ×× 10-3mol
The mole ratio NaOH : HCl = 1:1.
The amount of NaOH present in moles is 8.75 × 10-3mol.
Now we have the equation,
Molar Concentration = Amount in Moles / Volume of Solution
First convert the volume of aqueous NaOH into dm-3
25 cm3 = 25 / 1000 dm3
            = 25 × 10-3dm3
Therefore, the molar concentration of NaOH
           = 8.75×10−3 / 25.0×10-3
Molar concentration of NaOH = 0.350 mol dm-3
Example 2
The concentration of Ca(HCO3)2 is 0.85 gmol/L. Convert this concentration into geq/L.
Solution:
Given :
[C] = 0.85 gmol/ L
[C]eq = [C][MM] / eq.mass
MM = 40.1(2) + 2{1+12+3(16)}
  = 202.2
Number of reference species = 2
Therefore, eq.mass = Ca(HCO3)2 / 2
                 = 202.2 / 2
[C]eq = 0.85[202.2] / 202.2/2
= 1.7 geq/L
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