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Question

10 g of a mixture of sodium chloride and anhydrous sodium sulphate is dissolved in water. An excess of barium chloride solution is added and 6.99 g. of barium sulphate is precipitated according to the equation :-

Na2SO4+BaCl2BaSO4+2NaCl.
The percentage of sodium sulphate in the original mixture is:
[Na=23,O=16,S=32,Ba=132]

A
4.26 %
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B
42.6 %
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C
52.63 %
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D
5.26 %
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Solution

The correct option is D 42.6 %

Na2SO4+BaCl2BaSO4+2NaCl

Molecular weight of BaSO4=137+32+64=233

Molecular weight of Na2SO4=223+32+64=142

233gof BaSO4 is obtained from 142g of Na2SO4

6.99g of BaSO4 will be obtained from 142233×6.99 = 4.26g of Na2SO4

Percentage of Na2SO4 in 10g of mixture = 4.2610×100= 42.6%


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