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Question

100 ml of PH3 when decomposed produces phosphorus and hydrogen. The change in volume is:

A
50 ml increase
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B
500 ml decrease
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C
900 ml decrease
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D
none of the above
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Solution

The correct option is A 50 ml increase
The equation for the decomposition is:

4PH3(g)P4(s)+6H2(g) (Elemental phosphorus exists as tetra-atomic molecules).

When the temperature and pressure remain the same, 4 ml of PH3 will give 6 ml of H2. (On applying Gay-Lussac's law ).

Hence, 100 ml of PH3 will yield 150 ml of H2.

Increase in volume = (150-100) ml = 50 ml. (The volume of solid phosphorus is negligible).

Hence, the correct option is A

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