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Standard XII
Chemistry
Reaction with Metals
18. 10g of Mn...
Question
18. 10g of MnO2 on reaction with HCL forms 2.24L of chlorine gas at NTP, the percentage impurity of MnO2 is 1) 87% 2) 25% 3) 33.3% 4) 13%
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Q.
10
g
of
M
n
O
2
on reaction with HCI forms
2.24
L
of
C
I
2
(
g
)
at NTP, the percentage impurity of
M
n
O
2
is:
M
n
O
2
+
4
H
C
I
→
M
n
C
I
2
+
C
I
2
+
2
H
2
O
Q.
M
n
O
2
+
4
H
C
l
→
2
H
2
O
+
M
n
C
l
2
+
C
l
2
The reaction of
M
n
O
2
and
H
C
l
produces
2.24
L
of
C
l
2
gas. What mass of
M
n
O
2
was used up by the reaction? (At. mass of
M
n
=
55
g
/
m
o
l
)
Q.
8.7
g of pyrolusite (impure
M
n
O
2
) was heated with conc.
H
C
l
. The
C
l
2
gas evolved was passed through excess of
K
I
solution. The iodine gas evolved required
80
ml of
N
10
hypo solution. The percentage of
M
n
O
2
in pyrolusite will be :
Q.
10
g of
M
n
O
2
on reaction with conc.
H
C
l
liberated
0.1
equivalent of
C
l
2
(molecular weight of
M
n
=
55
g/mol). Hence, percentage purity of
M
n
O
2
is
:
Q.
Assertion :One equivalent of
M
n
O
2
reacts with 2 equivalents of
H
C
l
in the reaction,
M
n
O
2
+
4
H
C
l
⟶
M
n
C
l
2
+
2
H
2
O
+
C
l
2
. Reason: One equivalent of
M
n
O
2
reacts with one equivalent of
H
C
l
.
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