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Question 2.29

Nalorphene (C19H21NO3), similar to morphine, is used combat withdrawal symptoms in narcotic users. Does of nalorphene generally given is 1.5 mg. Calculate the mass of 1.5×103 m aqueous solution required for the above dose.

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Solution

m=1.5×103mor1.5×103 mol kg1

Mass of solute =1.5×103g or 1.5 mg

Mass of solvent=?

Molar mass of solute

(C19H21NO3)=(12×19)+(1×21)+(14)+(16×3)

=311 g mol1

Number of moles of solute =MassMolar mass=(1.5×103g)(311 g mol1)

Molality (m) =Number of molesMass of solvent in kg

Mass of solvent =Number of molesMolality

=(1.5×103g)(311 g mol1)×1(1.5×103 mol kgg)

=1311=0.0032 kg or 3.2g


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