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Question

70 calories of heat are required to raise the temperature of 2 moles of an ideal gas at constant pressure from 30oC to 35oC. The amount of heat required to raise the temperature of same gas through the same range (30oCto35oC) at constant volume (R=2cal/mol/K) is:

A
30
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B
50
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C
70
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D
90
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Solution

The correct option is B 50
Given: Heat required to raise the temperature
QP=70cal
n=2moles
ΔT=5oC

QP=nCPΔT
70=2×CP×5
CP=7cal/mol/K

CV=5 (As for gas CPCV=R)

Now, that required to increase the temperature at constant volume,
QV=nCVΔT=2×5×5=50cal

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