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Standard XII
Chemistry
Central Atom and Ligands
71. .(CH3)₂C˙...
Question
71. .(CH3)₂C˙ CH₂CH₃ and (CH₃)₃C˙ among these two free radical which is more stable and why ?
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Q.
Consider the following statements :
(a)
C
H
3
O
⊕
C
H
2
is more stable than
C
H
3
⊕
C
H
2
(b)
M
e
2
⊕
C
H
is more stable than
C
H
3
C
H
2
⊕
C
H
2
(c)
C
H
2
=
C
H
−
⊕
C
H
2
is more stable than
C
H
3
C
H
2
⊕
C
H
2
(d)
C
H
2
=
⊕
C
H
is more stable than
C
H
3
⊕
C
H
2
Out of these statements :
Q.
Explain why
(
C
H
3
)
3
+
C
is more stable than
C
H
3
+
C
H
2
and
+
C
H
3
is the least stable cation.
Q.
IUPAC name of
C
H
3
−
C
H
=
C
H
−
C
H
=
C
=
C
H
−
C
H
=
C
=
C
=
C
H
−
C
H
3
is:
Q.
Which of the two: O
2
NCH
2
CH
2
O
–
or CH
3
CH
2
O
–
is expected to be more stable and why?
Q.
Among the following compounds identify the one which gives more heat of hydrogenation
C
H
3
−
C
H
=
C
H
−
C
H
3
(I) and
C
H
3
−
C
H
2
−
C
H
=
C
H
2
(II)
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