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Question

A fuel cell involves combustion of the butane at 1 atm and 298 K
C4H10(g)+132O2(g)4CO2(g)+5H2O(l)G=2746 kJ/mol
What is E of a cell?

A
+4.74 V
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B
+0.547 V
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C
+1.09 V
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D
+4.37 V
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Solution

The correct option is C +1.09 V
In the reaction
10+10C4H10(g)+132O2(g)+444CO2(g)+5H2O(l)
Change in oxidation number of carbon +16(10)=+26
Number of electrons involved in cell process will be 26.
E=GnF=(2746)×100026×96500=+1.09 V.

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