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Question

A gas expands isothermally against a constant external pressures of 1 atm from a volume of 10dm3 to a volume of 20dm3. It absorbs 800 J of thermal energy from its surroundings. Calculate the change in internal energy (ΔE).

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Solution

T=0 (isothermal process).
Internal energy change (E)=Q+W=nCVT
But as T=0,
Internal energy change (E)=nCVT=0
Therefore, for isothermal process, the change in internal energy (E) is always zero.

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