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Question

A metal carbonate X on reacting with an acid gives a gas which when passed through a solution Y gives the carbonate back. On the other hand, when a gas G obtained at the anode during electrolysis of brine is passed on dry Y, it gives a compound Z, used for disinfecting drinking water. Identity X, Y, G, and Z.

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Solution

When calcium carbonate reacts with hydrochloric acid, it gives carbon dioxide gas.
CaCO3+2HClCaCl2+CO2+H2O

When carbon dioxide is passed through limewater, the limewater turns milky. This happens because of the formation of calcium carbonate.
CO2+Ca(OH)2CaCO3+H2O

On electrolysis of brine, chlorine gas is obtained at the anode. When chlorine gas is passed through limewater, it gives bleaching powder.
Ca(OH)2+Cl2CaOCl2+H2O

X is calcium carbonate. Y is limewater. G is chlorine. Z is bleaching powder.

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