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Question

A reactant (A) forms two products :
Ak1B, Activation energy Ea1
Ak2B, Activation energy Ea2
[Assuming same value of pre-expotential factor (A) for both reactions]

A
k1=k2eEa1RT
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B
k2=k1eEa2RT
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C
k2=k1eEa1RT
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D
k1=2k2eEa2RT
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Solution

The correct option is A k1=k2eEa1RT
k1=k2eEa1RT
k1=AeEa1RT , k2=AeEa2RT
lnk1lnk2=Ea1RT+2Ea2RT
k1k2=eEa1RT
k1=k2eEa1RT


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