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Question

A reaction, A+BC+Dq, is found to have a positive entropy change, the reaction will be:

A
possible at high temperature
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B
possible only at low temperature
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C
not possible at any temperature
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D
possible at any temperature
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Solution

The correct option is A possible at high temperature
As reaction is endothermic,
A+BC+Dq
so ΔH=+ve
and if entropy change is positive then ΔS=+ve
so ΔG=ΔHTΔS<0 at high temperature and reaction will be possible at high temperature only.

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