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Question

A salt on reaction with dil. H2SO4 produces a colourless gas which turns lime water milky and an acidified orange coloured potassium dichromate solution green. The salt may be:

A
a carbonate
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B
a sulphite
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C
a sulphide
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D
an acetate
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Solution

The correct option is B a sulphite
The salt is sulphite. When the salt reacts with sulphuric acid, sulphur dioxide gas is liberated.
SO23+2H+SO2+H2O
This gas when reacts with lime water, turns milky.
SO2+Ca(OH)2CaSO3(white)+H2O
And, when it reacts with
an acidified orange colored potassium dichromate, solution turns green due to the formation of chromium ions.
Cr2O27+2H++3SO2Cr3++3SO24+H2O

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