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Question

A solid AB has NaCl structure. If the radius of cation is 100 pm, what will be the maximum radius of anion B−?

A
241.54 pm
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B
136.61 pm
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C
120.7 pm
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D
68.3 pm
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Solution

The correct option is A 241.54 pm
NaCl has coordination number of 6. Thus, radius ratio of AB will be between 0.414 and 0.732. For maximum radius,
r+r=0.414
100r=0.414
r=241.54 pm

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