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Question

A solid compound XY has NaCl structure. If the radius of the cation is 100pm, the radius of the anion (Y+) will be :

A
271.5pm
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B
322.5pm
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C
241.5pm
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D
220.5pm
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Solution

The correct option is C 241.5pm
NaCl has fcc arrangement in which Cl ions occupy the corners and face centres of a cube while Na+ ions are present at the edge centres and body centre.

Since XY has NaCl structure we have,

0.414 r+r ≤ 0.732

Given, r+=100pm

Therefore, r = r+0.414 = 100pm0.414

r=241.5pm

Hence, option C is correct.


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