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Standard XII
Chemistry
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Account for t...
Question
Account for the following:
Iron on reaction with
H
C
l
forms
F
e
C
l
2
and not
F
e
C
l
3
.
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Solution
Iron reacts with
H
C
l
to form
F
e
C
l
2
and
H
2
F
e
+
2
H
C
l
→
F
e
C
l
2
+
H
2
H
2
thus produced prevents the oxidation of
F
e
C
l
2
to
F
e
C
l
3
.
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Similar questions
Q.
Account for the following:
(i)
P
C
l
5
is more covalent than
P
C
l
3
.
(ii) Iron on reaction with
H
C
l
forms
F
e
C
l
2
and not
F
e
C
l
3
.
(iii) The two
O
−
O
bond lengths in the ozone molecule are equal.
Q.
Explain why, iron dissolves in
H
C
l
to form
F
e
C
l
2
and not
F
e
C
l
3
?
Q.
Identify the oxidant and the reductant in the following reaction respectively:
(
i
)
F
e
C
l
2
+
H
2
O
2
+
H
C
l
→
F
e
C
l
3
+
H
2
O
Q.
Assertion :
F
e
C
l
3
can be reduced to
F
e
C
l
2
by
S
n
C
l
2
as well as by the addition of
S
n
into it. Reason: This reaction is possible since
S
n
4
+
is more stable than
S
n
2
+
(inert-pair effect)Also,
F
e
C
l
3
solution is acidic due to hydrolysis.
S
n
added reacts with
H
C
l
forming nascent hydrogen that can reduce
F
e
C
l
3
to
F
e
C
l
2
Q.
Balance the following equation by ion electron method.
F
e
C
l
3
+
H
2
S
→
F
e
C
l
2
+
H
C
l
+
S
.
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