All form ideal solution except

C_{2} H_{5} B r

and

C_{2} H_{5} I

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C_{6} H_{5} C l

and

C_{6} H_{5} B r

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C_{6} H_{6}

and

C_{6} H_{5} C H_{3}

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C_{2} H_{5} I

and

C_{2} H_{5} O H

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Solution

The correct option is D $C_{2} H_{5} I$ and $C_{2} H_{5} O H$
The following forms an ideal solution
$C_{2} H_{5} B r + C_{2} H_{5} I$
$C_{6} H_{5} C l + C_{6} H_{5} B r$
$C_{6} H_{6} + C_{6} H_{5} C H_{3}$

$As we know, C_{2} H_{5} O H shows H-bonding as well as it is polar so it will not make an ideal solution.$

thus, the correct answer is D.

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Similar questions

Column - I	Column - II
a) A nearly ideal solution	p) $H_{2} O + C_{2} H_{5} O H$
b) A solution showing positive deviation	q) $C_{6} H_{6} + C_{6} H_{5} C H_{3}$
c) A solution showing negative deviation	r) $C_{6} H_{6} + C H C l_{3}$
d) An azeotropic mixture	s) $C H_{3} C O C H_{3}$ + $C_{2} H_{5} O H$
	t) $Δ H$ and $Δ V$ are positive
	u) $Δ H$ and $Δ V$ are negative