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Standard XII

Chemistry

Chlorides of Phosphorus

Among the fol...

Question

Among the following compounds, which will produce $P O C l_{3}$ with $P C l_{5}$ ?

Only

O_{2}

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O_{2}

and

C O_{2}

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C O_{2}, O_{2}

and

P_{4} O_{10}

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S O_{2}, H_{2} O, H_{2} S O_{4}

and

P_{4} O_{10}

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Solution

The correct option is B $S O_{2}, H_{2} O, H_{2} S O_{4}$ and $P_{4} O_{10}$
$P C l_{5}$ on reaction with the given compounds produce $P O C l_{3}$ .

$2 P C l_{5} + S O_{2} \to P O C l_{3} + S O C l_{2}$

$P C l_{5} + H_{2} O \to P O C l_{3} + 2 H C l$

$2 P C l_{5} + H_{2} S O_{4} \to S O_{2} C l_{2} + 2 P O C l_{3} + 2 H C l$

$6 P C l_{5} + P_{4} O_{10} \to 10 P O C l_{3}$ .

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Similar questions

Q. Among the following the number of compounds that can react with

P C l_{5}

to give

P O C l_{3}

is :

O_{2}, C O_{2}, S O_{2}, H_{2} O, H_{2} S O_{4}, P_{4} O_{10}

Among the following, the number of compounds that can react with $P C l_{5}$ to give $P O C l_{3}$ is $O_{2}, C O_{2}, S O_{2}, H_{2} O, H_{2} S O_{4}, P_{4} O_{10}$ .___

Q. Among the following, the number of compounds that can react with

P C l_{5}

to give

P O C l_{3}

is:

C_{2} H_{5} O H, S O_{2}, H_{2} O, H_{2} S O_{4}, P_{4} O_{10}

Q. The mass of

P_{4} O_{10}

produced, if

440

g of

P_{4} S_{3}

is mixed with

384 g m

O_{2}

, is:

P_{4} S_{3} + O_{2} \to P_{4} O_{10} + S O_{2}

Q. Balance the following equations:

M n O_{2} + H C l \to M n C l_{2} + C l_{2} + H_{2} O

N H_{4} C l + C a (O H)_{2} \to N H_{3} + C a C l_{2} + H_{2} O

B a C l_{2} + A l_{2} (S O_{4})_{3} \to B a S O_{4} + A l C l_{3}

N a A l O_{2} + H_{2} O + C O_{2} \to A l H_{3} + N a_{2} C O_{3}

N H_{3} + O_{2} \to N O + H_{2} O

Z n + H N O_{3} \to Z n (N O_{3})_{2} + N O_{2} + H_{2} O

H_{2} S + O_{2} \to H_{2} O + S O_{2}

P b O + C \to P b + C O_{2}

B a C l_{2} + H_{2} S O_{4} \to B a S O_{4} + H C l

C H_{4} + O_{2} \to C O_{2} + H_{2} O

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Among the following compounds, which will produce POCl3 with PCl5?

The correct option is B SO2,H2O,H2SO4 and P4O10PCl5 on reaction with the given compounds produce POCl3.2PCl5+SO2→POCl3+SOCl2PCl5+H2O→POCl3+2HCl2PCl5+H2SO4→SO2Cl2+2POCl3+2HCl6PCl5+P4O10→10POCl3.

Among the following compounds, which will produce $P O C l_{3}$ with $P C l_{5}$ ?