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Question

Among the following observations, the correct one that differentiates between SO23 and SO24 is:

A
Both form precipitate with BaCl2,SO23 dissolves in HCl but SO24 does not
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B
SO23 forms precipitate with BaCl2,SO24 does not
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C
SO24 forms precipitate with BaCl2,SO23 does not
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D
Both form precipitate with BaCl2,SO24 dissolves in HCl but SO23 does not
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Solution

The correct option is A Both form precipitate with BaCl2,SO23 dissolves in HCl but SO24 does not
BaCl2+SO24BaSO4+2Cl
BaCl2+SO23BaSO3+2Cl

SO23 and SO24 when treated with BaCl2, give white precipitate of BaSO4 respectively.
Out of these two, SO23 is soluble in HCl but SO24 does not.

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