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Question

Among the following, the correct statement (s) is (are) :
  1. Al(CH3)3 has the three - centre two - electron bonds in its dimeric structure
  2. The Lewis acidity of BCl3 is greater than that of AlCl3
  3. AlCl3 has the three centre two-electron bonds in its dimeric structure
  4. BH3 has the three centre two-electron bonds in its dimeric structure


Solution

The correct options are
A Al(CH3)3 has the three - centre two - electron bonds in its dimeric structure
B The Lewis acidity of BCl3 is greater than that of AlCl3
D BH3 has the three centre two-electron bonds in its dimeric structure
(A) Structure of Al2(CH3)6


(B) BCl3 is stronger lewis acid due to small size of boron.

(C) Structure of Al2Cl6

(D) Structure of B2H6

BH3 has the three centre two-electron bonds in its dimeric structure

 

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