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Question

Among the following, the molecules that have same shape is :

A
CO2 and ClO2
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B
NO2 and ClO2
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C
ClO2 and XeF2
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D
NO2 and XeF2
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Solution

The correct option is B NO2 and ClO2
Steric Number (x) = 12(M + V C+A).
where, M = number of monovalent surrounding atoms
V = number of valence electrons on the central atom
C = charge (with sign)
A=charge on anion
a) CO2
Steric Number (x)=12(4+00+0).
Steric Number (x)=2.
Hybridisation =sp
Shape- linear

b) NO2 has V-shaped structure.


c ClO2 has V-shaped structure.

XeF2 has linear structure.


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