Among the following, the strongest base is:

C_{6} H_{5} {N H}_{2}

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p - {N O}_{2} C_{6} H_{4} {N H}_{2}

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m - {N O}_{2} C_{6} H_{4} {N H}_{2}

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C_{6} H_{5} {C H}_{2} {N H}_{2}

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Solution

The correct option is B $C_{6} H_{5} {C H}_{2} {N H}_{2}$
(D) is an aliphatic amine; so it is stronger base than aromatic amine.

Moreover, EWG $(- {N O}_{2})$ at o, p and m-positions decreases the basic character.

The basicity order is:
$(D) > (A) > (C) > (B)$ .

Option D is correct.

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