The correct option is A C2H5S−
Nucleophiles are those substances which can donate a pair of electrons. These can be neutral or negative. The nucleophilic power depends on the tendency of species to donate electrons. This is more, when an electron pushing group (+I or, +Mgroup) is present and negative charge is on less electronegative atom so that electron pair is easily pushed.
Here, negative charge on less electronegative atom- S with electron releasing group (C2H5) is most nucleophilic in nature.
Hence, (a) is correct.