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Question

An alkyl bromide (A) forms Grignard reagent which on treatment with water, yields n-hexane. (A) On treatment with sodium forms 4,5-diethyloctane. (A) is:

A
CH3(CH2)5Br
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B
CH3(CH2)3CHBrCH3
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C
CH3(CH2)2Br|CHCH2CH3
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D
CH3(CH2)2Br|CHCH=CH2
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Solution

The correct option is C CH3(CH2)2Br|CHCH2CH3




The Grignard reagent is a strong base and is easily protonated to form alkane.

Alkyl bromide(A) undergoes a Wurtz reaction to give symmetrical alkane,4,5-diethyloctane.


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