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Standard XII
Chemistry
Reaction with Metals
An aqueous so...
Question
An aqueous solution of a complex compound of formula Co (NH3)5Br (SO4)reacts readily with aqueous AgNO3 to give a yellowish white precipitate.write down the structural formula of the complex and mention the reaction involved.
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Q.
Which of the following pairs of complexes whose aqueous solutions gives pale yellow and white precipitates respectively with
0.1
M
A
g
N
O
3
?
Q.
A complex compound of cobalt has molecular formula containing five
N
H
3
molecules, one
N
O
2
group and two
C
l
atoms for one
C
o
atom. One mole of this compound produces three moles of ions in aqueous solution. On reacting with an excess of
A
g
N
O
3
solution, two moles of
A
g
C
l
get precipitated. The ionic formula of the compound is:
Q.
A coordination complex compound of cobalt has the molecular formula containing five ammonia molecules, one nitro group and two chlorine atoms for one cobalt atom. One mole of this compound produces three mole ions in an aqueous solution. On reacting this solution with excess of
A
g
N
O
3
solution, we get two moles of
A
g
C
l
precipitate. The ionic formula for this complex would be:
Q.
Ammonia gas does not evolve from the complex
F
e
C
l
3
⋅
4
N
H
3
but it gives white precipitate with aqueous solution of
A
g
N
O
3
. Coordination number of central metal ion in above complex is six. Give IUPAC name of the complex:
Q.
An aqueous solution of titanium chloride, when subjected to magnetic measurement, measured zero magnetic moment. Assuming the octahedral complex in aqueous solution, the formulae of the complex is :
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