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Question

An electron in an excited state of Li2+ ion has angular momentum 3h2π. The de Broglie wavelength of the electron in this state is ρπa0 (where a0 is the Bohr radius). The value of ρ is

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Solution

mvr=3h2π
λ=2πr3
Also, λ=2πr3=2πa0n2lZ3(Qr=a0n2Z)
=2π3×a0(93)
=2πa0
ρ=2

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