An organic compound $A (C_{4} H_{9} C l)$ on reaction with $N a / d i e t h y l$ ether gives a hydrocarbon which on monochlorination gives only one chloro derivative than, $A$ is:

t -

butyl chloride

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sec. butyl chloride

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iso butyl chloride

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n -

butyl chloride

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Solution

The correct option is A $t -$ butyl chloride
To get only one Chloro derivative it should be $3^{\circ}$ Alkyl group.
$C_{4} H_{9} C l$ with Na / diethyl Ether is Wurtz reaction which gives Alkane.
Hence $C_{4} H_{9} C l$ is t-butyl Chloride.

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