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Question

Arrange the following carbanions in decreasing order of stability.

A
IV>III>I>II
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B
III>IV>II>I
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C
I>III>II>IV
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D
II>I>III>IV
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Solution

The correct option is A IV>III>I>II
The stability order of the carbanions can be determined using the M effect of the substituents present at the para position. Higher the M power of the substituents, higher will be the stability of the carbanion.

The order of M power of the substituents is:
NO2>CN>
CH3>OCH3 shows +M effect
Therefore, the stability order of the carbanions will be:
IV>III>I>II

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