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Question

Arrange the following in their decreasing order of acidity.

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A
III>IV>I>II
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B
I>II>III>IV
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C
IV>III>II>I
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D
II>III>I>IV
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Solution

The correct option is A III>IV>I>II
The decreasing order of acidity is III>IV>I>II.
In (III) +I effect of two Me groups makes it most basic
In (I) electron-withdrawing effect of the carbonyl group makes it less basic than ammonia.
In (II) electron-withdrawing effect of two (C=O) groups makes it least basic.

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