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Question

Assume equilibrium has been reached in the following reaction:
A(g)+B(g)C(g)+D(g)
On an increase in the pressure, the system will:

A
Shift to the products
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B
Shift to the reactants
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C
Not change because pressure never affects equilibrium positions
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D
Not change because there are equal number of moles of gas in reactant and product
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Solution

The correct option is D Not change because there are equal number of moles of gas in reactant and product
The given reaction is :-
A(g)+B(g)C(g)+D(g)
In this reaction, the no. of moles of gaseous species are same on reactants and product side. So, As per Le Chatelier's principle, pressure will have on effect on it.

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