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Byju's Answer
Standard XII
Chemistry
Van der Waal's Forces
At high press...
Question
At high pressure, van der Waal's equation for one mole of the gas becomes:
A
P
V
=
R
T
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B
P
V
=
R
T
+
a
V
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C
P
V
=
R
T
−
a
V
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D
P
V
=
R
T
+
P
b
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Solution
The correct option is
D
P
V
=
R
T
+
P
b
(
P
+
a
n
2
V
2
)
(
V
−
n
b
)
=
n
R
T
(
P
+
a
V
2
)
(
V
−
b
)
=
R
T
for 1 mol gas
At high pressure,
(
P
+
a
V
2
)
=
P
∴
P
(
V
−
b
)
=
R
T
P
V
=
R
T
+
P
b
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