Synthesis of Aldehydes or Ketones from Hydrocarbons
C6H5CH3 A BIn...
Question
C6H5CH3CrO2Cl2−−−−−→AOH⊝−−−→B
In the above reaction sequence, the conversion of A to B is called as ?
A
Cannizaro reaction
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B
Aldol condenation
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C
Clemmensen reduction
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D
Etard reaction
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Solution
The correct option is A Cannizaro reaction In the given reaction sequence, A is benzaldehyde (no alpha hydrogens). Aldehydes containing no α-hydrogen undergo Cannizaro reaction in presence of a base. So, A to B conversion is a Cannizzaro reaction.