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B
ΔH=−4Kcalmol−1
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C
ΔH=16Kcalmol−1
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D
None of these
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Solution
The correct option is AΔH=4Kcalmol−1 The balanced chemical equation for the formation of ICl is as shown. 12Cl2(g)+12I2(s)⟶ICl(g).....ΔfH=? The balanced chemical equations for the dissociation and sublimation are as shown. 1/21/21/2⎧⎪
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⎪⎩I2(g)⟶2I(g);ΔH1=36.1×1/2Cl2(g)⟶2Cl(g);ΔH2=57.9×1/2I2(s)⟶I2(g)+Cl(g);ΔH3=15.0×1/2ICl(g)⟶I(g)+Cl(g);ΔH4=50.5 The enthalpy change for the formation of ICl(g) is ΔH=(ΔH1+ΔH2+ΔH3)−ΔH4