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Question

Calculate ΔGo for the following reaction:
CO(g)+12O2(g)CO2(g);ΔHo=282.84kJ
Given, SoCO2=213.8JK1mol1,SoCO(g)=197.9JK1mol1,SoO2=205.0JK1mol1

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Solution

ΔSo=So(products)Soreactants
=[SoCO2][SoCO(g)+12SoO2]
=213[197.9+12×205]=86.6JK1
According to Gibbs-Helmholtz equation
ΔGo=ΔHoTΔSo=282.84298×(86.6×103)
=257.033kJ

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