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Question

Calculate the increase in the internal energy of 20 g of water when it is heated from 0C to 100C and converted into steam at 100 kPa. The density of steam =0.50 kg/m3, specific heat capacity of water =4200 J kg1C1 and latent heat of vaporization of water =2.3×106 J/kg

A
54.4 kJ
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B
4 kJ
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C
50 kJ
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D
60 kJ
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Solution

The correct option is C 50 kJ
From 1st law of thermodynamics,
Q=ΔU+W
or ΔU=QW
Now, net heat supplied to the system
Q=mCΔT+mL
=(201000×4200×100)+201000×2.3×106
=8400+46000=54400 J
Work done W=PΔV=P(V2V1)=P(mρ2mρ1)
=100×103[0.020.50.021000]
4000 J
[density of water =1000 kg/m3]
So, ΔU=QW
=544004000=50400
=5.04×104 J
50 kJ

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