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Question

Chlorine atoms in the upper atmosphere cause the breakdown of ozone.
Cl+O3O2+ClO
ClO+OCl+O2
Which statements are correct when referring to these chlorine atoms?
1. The chlorine atoms act as catalysts.
2. The chlorine atoms are free radicals.
3. The chlorine atoms are formed by heterolytic fission of a covalent bond in chlorofluorocarbons.

A
1,2 and 3 are correct
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B
1 and 2 only are correct
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C
2 and 3 only are correct
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D
1 only is correct
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Solution

The correct option is B 1 and 2 only are correct
In the given reaction, i.e., decomposition of ozone, the chlorine atoms are free radicals and acts as catalysts.
Chlorine initiates the breakdown of ozone and combines with a freed oxygen to create two oxygen molecules.
Hence only 1 and 2 are correct.

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