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Question

[Co(NH3)6][Cr(CN)6] and [Cr(NH3)6][Co(CN)6] are:

A
linkage isomers
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B
ionization isomers
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C
coordination isomers
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D
none of these
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Solution

The correct option is C coordination isomers
This type of isomerism is observed in the coordination compounds having both cationic and anionic complex ions. The ligands are interchanged in both the cationic and anionic ions to form isomers.
[Co(NH3)6][Cr(CN)6] [Co(NH3)6][Cr(C2O4)3]
[Cr(NH3)6][Co(CN)6] [Cr(NH3)6][Co(C2O4)3]

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