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Question

Compound (A) is:

256735_acaa494474b34546aff9da6c47fef425.png


A
CH3OCH3|C|CH3CH2CH2Br
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B
CH3CH|CH3CH|OCH3CH2Br
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C
CH3CH|CH3CH2CH|OCH3Br
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D
CH3OCH3|C|CH3CH|BrCH3
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Solution

The correct option is A $$\displaystyle { CH }_{ 3 }-\overset { \overset { { OCH }_{ 3 } }{ | } }{ \underset { { \underset { { CH }_{ 3 } }{ | } } }{ C } } -{ CH }_{ 2 }{ CH }_{ 2 }Br$$
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i. 2-Methoxy-2-methyl propane is obtained by the oxidation of (D) followed by decarboxylation, and thus (D) is 
$$CH_3 - \underset{CH_3}{\underset{|}{\overset{OCH_3}{\overset{|}{C}}}} - CH_2CH_2OH$$
ii. (D) is formed by the action of $$HNO_{2}$$ on (B), thus (B) is 
$$CH_3 - \underset{CH_3}{\underset{|}{\overset{OCH_3}{\overset{|}{C}}}} - CH_2CH_2NH_2$$
iii. (B) is formed by the action of $$NH_{3}$$ over (A), a bromoderivative.
$$(A) \Rightarrow CH_3 - \underset{CH_3}{\underset{|}{\overset{OCH_3}{\overset{|}{C}}}} - CH_2CH_2Br$$
Reactions :
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Option A is correct.

245969_256736_ans_956c32ab3b9141ef8d73d757b048d245.JPG

Chemistry

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