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Question

Consider the parallel first order reactions given above.
The half-life for the decay of A is _________ hrs.
662121_cf41eee5d4214b3c9ea07527f52769fd.png

A
1
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B
3
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C
4
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D
12
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Solution

The correct option is B 3
For parallel first order reaction,
dAdt=(k1+k2)[A]=k[A]
t1/2=In2k=In2k1+k2
=In2In2(t1/2)1+In2(t1/2)2=(t1/2)1×(t1/2)2(t1/2)1+(t1/2)2
=4×124+12 =3 hrs

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