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Question

During the adsorption of a gas on the surface of a solid, which of the following is true?

A
ΔG<0, ΔH>0, ΔS<0
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B
ΔG>0, ΔH<0, ΔS<0
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C
ΔG<0, ΔH<0, ΔS<0
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D
ΔG<0, ΔH<0, ΔS>0
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Solution

The correct option is C ΔG<0, ΔH<0, ΔS<0
ΔG<0 - process is spontaneous. Because adsorption is exothermic, ΔH=ve and the entropy decreases since the gas gets ordered, i.e., ΔS is -ve.

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