The Law of Independent Assortment states that when two pairs of traits are combined in a hybrid, one pair of characters segregates independent of the other pair of characters.
Mendel achieved this by conducting dihybrid crosses. He got a ratio of 9:3:3:1 in the F2 generation with new recombinants, which were not present in the parents or F1 generations. This shows that inheritance of one pair of alleles is independent of the other, thus generating new combinations or recombinants.