Enthalpy of neutralization of the reaction between CH3COOH(aq) and NaOH(aq) is −13.2Kcaleq−1 and that of reaction between H2SO4(aq) and KOH(aq) is −13.7Kcaleq−1. The enthalpy of dissociation of CH3COOH(aq) is:
A
−0.5kcaleq–1
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B
+0.5kcaleq–1
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C
−26.9kcaleq–1
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D
+13.45kcaleq–1
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Solution
The correct option is B+0.5kcaleq–1
Dissociation enthalpy of CH3COOH = 13.7−13.2 = 0.5kcaleq–1