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Question

Equal masses of methane and oxygen are mixed in an empty container at 25C. The fraction of total pressure exerted by oxygen is :

A
1/3
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B
1/2
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C
2/3
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D
13×273298
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Solution

The correct option is A 1/3
The fraction of total pressure exerted by oxygen will be equal to mole fraction of oxygen gas present in mixture of CH4 and O2.
Partial pressure of a component = Mole fraction × total pressure
Partial pressure of O2 / Total pressure = mole fraction of O2=(m/32)(m/32+m/16)=1/3

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