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Question

Equilibrium, X2Y and ZP+Q are established with 1 mole of Z and Z taken initially in separate vessels with equilibrium pressures of 1 atm and 36 atm respectively. If the degree of dissociations are same. Then KP2=nKP1. What is the value of n?

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Solution

X2YZP+Q
EqlbmPressure 1 atm 2 atm 36 atm 36 atm

Kp1=P2YPX,Kp2=PP×PQPZ
Kp1=41,Kp2=36×3636
Kp1=4,Kp2=36
Kp2kp1=364=9
Kp2=9Kp1
Compare with Kp2=nKp1
n=9

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