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Question

Ethanol when reacted with PCl5 gives (A), POCl3 and HCl. (A) reacts with silver nitrite to form (B) (major product) and AgCl. (A) and (B) are respectively.

A
C2H5Cl and C2H5OC2H5
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B
C2H6 and C2H5OC2H5
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C
C2H5Cl and C2H5NO2
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D
C2H6 and C2H5NO2
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Solution

The correct option is B C2H5Cl and C2H5NO2
The required reactions are:

C2H5OH+PCl5C2H5Cl(A)+POCl3+HCl

C2H5Cl+AgNO2C2H5NO2(B)+AgCl

Hence, option C is correct.

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